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Why does Thorne hate Sam so much? I know he supported Snow in the election but pretty sure he hated him before that s well.
Because Sam is physically & mentally (albeit much less so) weak. Thorne feels Sam is much more of a drag than an benefit. Aemon say Sam's potential, but Thorne is a ranger officer.
On Jon, I think Thorne thought Jon worthy as a brother, but has a thing against cocky highborn lordlings. Which Jon certainly was when he first got there. So Thorne was bent on knocking Jon down a peg, Jon stood up (which Thorne REALLY hated), and now, despite Thorne's best humbling efforts, Jon has risen to Lord Commander.