Thick cut bone-in pork chops are the absolute best use of sous vide IMO. I do steaks sous vide a fair amount as well, but the benefits from pork are better.
Depending on the flavors I'm going for, I usually put some fresh Thyme sprigs on the chops while they're in the bath at 141.5 for 1-4 hours.
One tip is when you remove from the bag and pat dry before your sear, make a few scores in the outer fat cap to help the chop stay flat during the sear.
After searing, you can go different directions for your pan sauce but my favorite is to deglaze with white wine and maybe a splash of something stronger like brandy or cognac, then add some minced garlic and/or shallots, thyme and/or herbs de Provence, maybe some chicken stock, and Dijon mustard. Reduce a bit, add some cream if you have it, and then serve on the chops. I've played around with the sauce ingredients and proportions a good bit, but the key is deglazing with wine and then adding the Dijon if you want that French country style flavor.
Also recently did a version of this Greek chicken recipe which turned out really well:
https://sousvideways.com/sous-vide-greek-chicken/